6,589 research outputs found
Preparation of a Semiquinonate-Bridged Diiron(II) Complex and Elucidation of its Geometric and Electronic Structures
The synthesis and crystal structure of a diiron(II) complex containing a bridging semiquinonate radical are presented. The unique electronic structure of this S = 7/2 complex is examined with spectroscopic (absorption, EPR, resonance Raman) and computational methods
Synthesis and Spectroscopic Characterization of High-Spin Mononuclear Iron(II) \u3cem\u3ep\u3c/em\u3e-Semiquinonate Complexes
Two mononuclear iron(II) p-semiquinonate (pSQ) complexes have been generated via one-electron reduction of precursor complexes containing a substituted 1,4-naphthoquinone ligand. Detailed spectroscopic and computational analysis confirmed the presence of a coordinated pSQ radical ferromagnetically coupled to the high-spin FeII center. The complexes are intended to model electronic interactions between (semi)quinone and iron cofactors in biology
Postgraduate nurses’ insights into the nursing leadership role. Do they intuitively link the role to patient safety?
Nursing leaders are compelled to ensure a safety and quality agenda in the acute care environment as patient outcomes are linked to nursing care. Good nursing leadership where focus is directed to accountability and responsibility for clinical outcomes and patient safety, results in reduced adverse events and patient mortality. Integral to the future of high-quality effective clinical care with an absence of errors is the training of the next generation of nursing leaders. In this discussion paper, the extent to which future nurse leaders intuitively acknowledge patient safety as part of their leadership role was examined amongst a cohort of postgraduate nursing students. A content analysis to search for quality and safety terminology was conducted on 146 essay responses to a question about the nurse leader role in today’s healthcare environment. The results indicated minimal acknowledgement of patient safety as an intuitive consideration in the nursing leadership role. Recommendations are discussed for developing postgraduate nursing educational curricula with patient safety strategies as a central component to the practice of leadership
Unit Killing Vector Fields on Nearly Kahler Manifolds
We study 6-dimensional nearly Kahler manifolds admitting a Killing vector
field of unit length. In the compact case it is shown that up to a finite cover
there is only one geometry possible, that of the 3--symmetric space
Cycles in the chamber homology of GL(3)
Let F be a nonarchimedean local field and let GL(N) = GL(N,F). We prove the
existence of parahoric types for GL(N). We construct representative cycles in
all the homology classes of the chamber homology of GL(3).Comment: 45 pages. v3: minor correction
Matrix elements of the electromagnetic operator between kaon and pion states
We compute the matrix elements of the electromagnetic (EM) operator between
kaon and pion states, using lattice QCD with maximally twisted-mass fermions
and two flavors of dynamical quarks (Nf = 2). The EM operator is renormalized
non-perturbatively in the RI'/MOM scheme and our simulations cover pion masses
as light as 260 MeV and three values of the lattice spacing, ranging from ~
0.07 up to ~ 0.1 fm. At the physical point our preliminary result for the K ->
pion tensor form factor at zero-momentum transfer is fT[K\pi](0) =
0.42(2_stat), which differs significantly from the old quenched result
fT[K\pi](0) = 0.78(6) obtained by the SPQcdR Collaboration with pion masses
above 500 MeV. We investigate the source of this difference and conclude that
it is mainly related to the chiral extrapolation of the quenched data. For the
case of the tensor charge of the pion we obtain the preliminary value
fT[\pi\pi](0) = 0.200(14_stat), which can be compared with the result
fT[\pi\pi](0) = 0.216(34) obtained at Nf = 2 by the QCDSF Collaboration using
higher pion masses.Comment: 7 pages, 5 figures, contribution to the XXVIII International
Symposium on Lattice Field Theory, Lattice2010, June 14-19, 2010,
Villasimius, Ital
Holomorphic Supercurves and Supersymmetric Sigma Models
We introduce a natural generalisation of holomorphic curves to morphisms of
supermanifolds, referred to as holomorphic supercurves. More precisely,
supercurves are morphisms from a Riemann surface, endowed with the structure of
a supermanifold which is induced by a holomorphic line bundle, to an ordinary
almost complex manifold. They are called holomorphic if a generalised
Cauchy-Riemann condition is satisfied. We show, by means of an action identity,
that holomorphic supercurves are special extrema of a supersymmetric action
functional.Comment: 30 page
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